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柴文祥

作者: 时间:2009-09-30 点击数:

姓 名:柴文祥

工作部门:69福利院区小猫影视

性 别:男

技术职称:副教授

最高学位:博士

民 族:汉

籍 贯:浙江富阳

联系方式:

Email: wxchai@cjlu.edu.cn

电 话:0571-86835738


主要研究方向:


学习和工作经历:

1998.09 - 2002.06 浙江大学应用化学专业从事本科阶段学习;

2002.09 - 2007.06 中国科学院福建物质结构研究所,结构化学国家重点实验室,攻读博士学位(导师陈玲研究员和吴新涛院士);

2007.07 - 至今 中国计量大学69福利院区小猫影视从事教学科研工作。


研究(情况)项目:

1.基于有机染料的耐久性光致变色杂化材料合成和构效关系,国家自然科学基金项目,批号:20803070(主持),2008年;

2. 基于比率荧光传感技术的便携式胺类VOC检测系统研发,浙江省科技计划项目,批号:LGF21B010001(主持),2020年;

3. 研发低成本磷光粉推进绿色节能OLED照明,浙江省科技计划项目,批号:2015C33047(主持),2015年;

4. 基于OLED的Cu(I)配合物结构设计与调控及发光机理研究,浙江省自然科学基金面上项目,批号:LY12E02010(主持),2012年;

5. 单分子磁体的结构与磁谱分析,浙江省科技计划项目,批号:2008F70051(主持),2008年。


发表的论文、专著、教材:

1. Wang, Y.-Y.; Song, L.; Dai, Z.-Q.; Xu, J.-C.; He, J.; Liu, W.; Shen, H.-Y.; Chai, W.-X., Synthesis, crystal structure, optoelectric properties and theoretical study of three perovskite-like iodobismuthate charge-transfer salts based on butylpyridinium. Journal of Solid State Chemistry 2021, 304, 122611.

2. Dai, D.-Q.; Song, L.; Liang, Y.; Wang, J.-T.; Zhou, Y.-M.; Shen, H.-Y.; Chai, W.-X., Heteroleptic cuprous complexes of a diimine MePBO ligand and their structure influence on phosphorescent color: Syntheses, structure characterizations, properties and TD-DFT calculations. Zeitschrift für anorganische und allgemeine Chemie 2021, 647, (19), 1896-1905.

3. Wang, D.-D.; Song, L.; Wang, Y.-Y.; Guo, J.-Y.; Shen, H.-Y.; Wang, X.-R.; Chai, W.-X., Heteroleptic [Cu(NN)P2]+-type cuprous complexes and their structural modulation on phosphorescent color: Synthesis, structural characterization, properties, and theoretical calculations. Applied Organometallic Chemistry 2020, 34, (4), e5561.

4. Wang, D.-D.; Zhu, Q.-M.; Song, L.; Guo, J.-Y.; Shen, H.-Y.; Wang, X.-R.; Chai, W.-X., A new series of three-coordinate cuprous complexes formed by steric hindrance of a phosphine ligand: Synthesis, structure characterization, properties and TD-DFT calculations. Polyhedron 2020, 175, 114178.

5. Jiang, Y.-X.; Wang, Y.-Y.; Song, L.; Wang, D.-D.; Guo, J.-Y.; Shen, H.-Y.; Wang, X.-R.; Chai, W.-X., The Optical Band-Gap Evolution in Perovskite-Like Hybrid Iodobismuthates Effected by Nuclearity and Dimension: An Experimental and DFT Calculation Study. J Clust Sci 2019, 30, (6), 1443-1454.

6. Song, L.; Wang, Y.-J.; Chai, W.-X., A diamond-type metal-organic framework based on nano-sized Cu-8(mu(4)-I)(6)(PPh3)(4) (2+) clusters and cyanide-ion linkers: Design, structure and luminescent property. Inorganic Chemistry Communications 2019, 104, 190-196.

7. Tao, X.-D.; Chai, W.-X.; Song, L.; Wei, Q.-H.; Shi, H.-S.; Qin, L.-S., Two luminescent pseudo-polymorphic cuprous complexes with different optical properties: Synthesis, characterization and TD-DFT calculations. Polyhedron 2018, 144, 36-43.

8. Zhu, Q.-M.; Song, L.; Chai, W.-X.; Shen, H.-Y.; Wei, Q.-H.; Qin, L.-S., A novel luminescent ionic trinuclear Cu3I2 cluster cuprous complex supported by a P^N ligand: synthesis, structure characterization, properties and TD-DFT calculations. Acta Crystallographica Section C 2018, 74, (1), 62-68.

9. Shou, R.-E.; Chai, W.-X.; Song, L.; Qin, L.-S.; Shi, H.-S.; Wang, T.-G., Three Luminescent Copper(I) Iodide Clusters with Phosphine Ligands: Synthesis, Structure Characterization, Properties and TD-DFT Calculations. J Clust Sci 2017, 28, (4), 2185-2203.

10. Chai, W.; Zhang, X.; Song, L.; Hong, M.; Shi, H.; Wang, C.; Guo, J.; Zheng, X.; Chen, G.; Shu, K., Modulating luminescence spectra by controlling the π∙∙∙π stacking strength of the excimers of a new europium complex material. Materials Letters 2015, 145, (0), 4-6.

11. Chai, W.; Hong, M.; Song, L.; Jia, G.; Shi, H.; Guo, J.; Shu, K.; Guo, B.; Zhang, Y.; You, W.; Chen, X., Three Reversible Polymorphic Copper(I) Complexes Triggered by Ligand Conformation: Insights into Polymorphic Crystal Habit and Luminescent Properties. Inorganic Chemistry 2015, 54, (9), 4200-4207.

12. Zhang, X.; Song, L.; Hong, M.; Shi, H.; Xu, K.; Lin, Q.; Zhao, Y.; Tian, Y.; Sun, J.; Shu, K.; Chai, W., Luminescent dinuclear copper(I) halide complexes double bridged by diphosphine ligands: Synthesis, structure characterization, properties and TD-DFT calculations. Polyhedron 2014, 81, (0), 687-694.


科研成果及专利:

1. 国家发明专利:一种基于亚铜配合物的VOC荧光传感材料,专利号:ZL 2019102312621 排名 2(学生第一);

2. 国家发明专利:一种对4-甲基吡啶蒸汽选择性响应的亚铜配合物荧光传感材料,专利号:ZL 2019102253962 排名 2(学生第一);

3. 国家发明专利:一种银碘阴离子高聚螺旋链基有机无机杂化半导体材料, 专利号:ZL 2016103071402 排名 1;

4. 国家发明专利:一种有机无机杂化亚铜碘阴离子高聚链基半导体材料, 专利号:ZL 2016103071953 排名 1;

5. 国家发明专利:一种有机无机杂化铋碘阴离子簇基半导体材料, 专利号:ZL 2016103072373 排名 1;

6. 国家发明专利:一种稀土金属有机框架结构的红外发光材料, 专利号:ZL 2016103071366 排名 1;

7. 国家发明专利:一种基于稀土金属有机框架结构的绿色荧光材料, 专利号:ZL 2016103072227 排名 1;


研究生培养等教学情况:

1.已培养数名材料科学与工程学硕和光学工程专硕;

2.主讲《普通化学A》和《有机化学》课程。


奖励和荣誉:

1. 2011学校第十一届青年园丁奖;

2. 2016校级创新与实践活动优秀指导教师。


其它:


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